3-[(8-Butoxyquinolin-2-yl)methyl]-1-(pyridin-2-ylmethyl)-1H-imidazol-3-ium hexafluoridophosphate
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چکیده
منابع مشابه
3-[(8-Butoxyquinolin-2-yl)methyl]-1-(pyridin-2-ylmethyl)-1H-imidazol-3-ium hexafluoridophosphate
In the cation of the title compound, C(23)H(25)N(4)O(+)·PF(6) (-), the imidazolium ring make dihedral angles of 87.20 (6) and 79.89 (5)° with the pyridine ring and the quinoline system, respectively. In the crystal, C-H⋯F and C-H⋯N hydrogen bonds are observed.
متن کامل3-(2-Bromobenzyl)-1-methyl-1H-imidazol-3-ium bromide
In the title compound, C(11)H(12)BrN(2) (+)·Br(-), the imidazole and phenyl rings are nearly perpendicular, making a dihedral angle of 87.71 (7)°. The crystal structure is stabilized by non-classical inter-molecular C-H⋯Br hydrogen bonds and inversion-related mol-ecules are linked through π-π inter-actions between the imidazole ring systems [centroid-centroid distance = 3.472 (6) Å].
متن کامل[1-tert-Butyl-3-(pyridin-2-ylmethyl-κN)imidazol-2-ylidene-κC 1]carbonyldichlorido(dimethyl sulfoxide-κS)ruthenium(II)
In the title complex, [RuCl(2)(C(13)H(17)N(3))(C(2)H(6)OS)(CO)], the coordination environment around the Ru atom is slightly distorted octa-hedral. The Cl atoms are mutually trans to the dimethyl sulfoxide ligand and the imidazole carbene C atom, respectively. The carbonyl ligand is located trans to the pyridine N atom.
متن کاملBis[2-(1H-imidazol-2-yl-κN 3)-1H-imidazol-3-ium]silver(I) trinitrate
The synthesis of the title salt, [Ag(C(6)H(7)N(4))(2)](NO(3))(3), was carried out employing a 1:2 molar ratio of 2,2'-biimidazole and silver nitrate respectively. The cation has crystallographically-imposed C2 symmetry with the metal atom in an almost linear coordination environment [N-Ag-N = 177.01 (17)°]. The crystal structure displays N-H⋯O and C-H⋯O hydrogen-bonding inter-actions.
متن کاملCrystal structures of the two salts 2-methyl-1H-imidazol-3-ium nitrate–2-methyl-1H-imidazole (1/1) and 2-methyl-1H-imidazol-3-ium nitrate
The title salts, C4H7N2 (+)·NO3 (-)·C4H6N2, (I), and C4H7N2 (+)·NO3 (-), (II), were obtained from solutions containing 2-methyl-imidazole and nitric acid in different concentrations. In the crystal structure of salt (I), one of the -NH H atoms of the imidazole ring shows half-occupancy, hence only every second mol-ecule is in its cationic form. The nitrate anion in this structure lies on a twof...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2012
ISSN: 1600-5368
DOI: 10.1107/s1600536812013414